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All-inorganic TiO/CsAgBiBr composite as highly efficient photocatalyst under visible light irradiation

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12, Pages 1925-1936 doi: 10.1007/s11705-023-2344-6

Abstract: A leading star in photocatalysis has been revealed as lead-free Cs2sub>AgBiBr6sub> doubleIn this work, this photocatalytic process was facilitated by a unique TiO2sub>/Cs2sub>AgBiBr6sub> composite, which was identified as an S-cheme heterojunction.TiO2sub>/Cs2sub>AgBiBr6sub> composite was investigated for its structure and photocatalytic>2sub>/Cs2sub>AgBiBr6sub> composites, which will facilitate the generation of new ideas

Keywords： Cs2sub>AgBiBr6sub> nanocrystals visible-light photocatalyst Cs2sub>AgBiBr6sub>/TiO2sub> heterojunction

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Cu-doped Bi/Bi2sub>WO6sub> catalysts for efficient N2sub> fixation by photocatalysis

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1412-1422 doi: 10.1007/s11705-023-2312-1

Abstract: In this paper, Cu-doped Bi2sub>WO6sub> was synthesized via a solvothermal method and applied>2sub>WO6sub> composite.>2sub>WO6sub>.The optimized NH3sub> generation rates of Bi/Cu-Bi2sub>WO6sub> reached 624 and 243>2sub>WO6sub>, respectively.

Keywords： Bi2sub>WO6sub> Cu doping work function photocatalytic N2sub> fixation charge

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ZnFe2sub>O4sub>/BiVO4sub> Z-scheme heterojunction for efficient visible-light photocatalytic

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11, Pages 1728-1740 doi: 10.1007/s11705-023-2322-z

Abstract: A novel Z-scheme ZnFe2sub>O4sub>/BiVO4sub> heterojunction photocatalyst was successfullyCompared with the single-phase counterparts, ZnFe2sub>O4sub>/BiVO4sub> demonstratedConsequently, the 30% ZnFe2sub>O4sub>/BiVO4sub> catalyst afforded a degradationMoreover, the as-synthesized ZnFe2sub>O4sub>/BiVO4sub> heterojunctions were quiteThis study thus provides a promising Z-scheme heterojunction photocatalyst for the efficient removal

Keywords： ZnFe2sub>O4sub>/BiVO4sub> Z-scheme heterojunction photocatalytic degradation

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In-MOF-derived In2sub>S3sub>/Bi2sub>S3sub> heterojunction for enhanced photocatalytic

Frontiers in Energy 2023, Volume 17, Issue 5, Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: In this paper, a broad spectrum responsive In2sub>S3sub>/Bi2sub>S3sub> heterojunctionis constructed by in-situ integrating Bi2sub>S3sub> with the In2sub>S2sub>S3sub>/Bi2sub>S3sub> heterojunction demonstrates a rate of 0.71 mmol/(g∙h), which is 2.2 and 1.7 times as much as those of In2sub>S3sub> (0.32 mmol/(g∙h) and Bi2sub>S3sub> (0.41 mmol/(g∙h)), respectively.

Keywords： photocatalytic hydrogen production wide-spectrum response metal sulfides MOFs derivative heterogeneous interfacial contact

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Interfacial charge transfer and photocatalytic activity in a reverse designed BiO/TiO core-shell

Frontiers in Energy 2021, Volume 15, Issue 3, Pages 732-743 doi: 10.1007/s11708-021-0772-x

Abstract: >2sub> and Bi2sub>O3sub> layers were studied.The results show the formation of homogenous TiO2sub> anatase and Bi2sub>O3sub>In optimal core-shell design, Bi2sub>O3sub> collects holes from TiO2sub>, leavingelectrons free to react and increase by 5 times the photocatalytic efficiency toward H2sub> generationThis study provides new insight into the importance of the design and elaboration of optimal heterojunction

Keywords： photocatalysis core-shell heterojunction H2sub> TiO2sub> Bi2sub>O3sub

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Piezocatalytic performance of FeO−BiMoO catalyst for dye degradation

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 6, Pages 716-725 doi: 10.1007/s11705-022-2265-9

Abstract: A Fe2sub>O3sub>−Bi2sub>MoO6sub> heterojunction was synthesized via a hydrothermalBi2sub>MoO6sub> composite catalyst under 60 min of ultrasonic vibration.>2sub>O3sub> and Bi2sub>MoO6sub>, which effectively separated the ultrasound-induced>3sub>−Bi2sub>MoO6sub> catalyst was proposed based on the band potential and quenchingThe results demonstrated the potential of using Fe2sub>O3sub>−Bi2sub>MoO6

Keywords： piezocatalysis Fe2sub>O3sub>−Bi2sub>MoO6sub> dye decomposition ultrasonic

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Enhanced performance of NiF/BiVO photoanode for photoelectrochemical water splitting

Frontiers in Energy 2021, Volume 15, Issue 3, Pages 760-771 doi: 10.1007/s11708-021-0781-9

Abstract: >4sub> photoanode restrict its photoelectrochemical (PEC) water splitting performance.In this work, nickel fluoride (NiF2sub>) is applied to revamp pure BiVO4sub> photoanodeAs a result, the as-prepared NiF2sub>/BiVO4sub> photoanode increases the dramatic photocurrentdensity by approximately 180% compared with the pristine BiVO4sub> photoanode.>2sub> and BiVO4sub>.

Keywords： BiVO4sub> NiF2sub> heterojunction photoelectrochemical water splitting

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Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4, Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords： Rh2sub>O3sub> CePO4sub> N2sub>O decomposition

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CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2, Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

Keywords： Mn promotion nickel catalysts CO2sub> methanation co-methanation of CO and CO2sub>

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g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 2, Pages 217-225 doi: 10.1007/s11705-022-2214-7

Abstract: Herein, superior α-MnO2sub>@g-C3sub>N4sub> was successfully prepared forstable zinc-ion batteries (ZIBs) cathode by introducing g-C3sub>N4sub> nanosheets.Compared with pure α-MnO2sub>, α-MnO2sub>@g-C3sub>N4sub> hasEven at 1 A·g^–1, the α-MnO2sub>@g-C3sub>N4sub> still retains 100The α-MnO2sub>@g-C3sub>N4sub>-based cathode has the highest energy density

Keywords： α-MnO2sub> hollow nanorods g-C3sub>N4sub> heterojunction aqueous Zn-ion

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A Storage-Driven CO2sub> EOR for a Net-Zero Emission Target Article

Yueliang Liu, Zhenhua Rui

Engineering 2022, Volume 18, Issue 11, Pages 79-87 doi: 10.1016/j.eng.2022.02.010

Abstract: >2sub>) emissions.>2sub> emissions by storing CO2sub> in oil reservoirs.CO2sub> EOR—whose main target is to realize net-zero or even negative CO2sub> emissionsStorage-driven CO2sub> EOR is superior to conventional CO2sub> EOR in improving sweepingthan conventional CO2sub> EOR.

Keywords： CO2sub> EOR Net CO2sub> emissions Dimethyl ether Storage-driven CO2sub> EOR CO2sub> sequestration

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Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1, Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

Keywords： CO2sub> capture MgO sorbents Al2sub>O3sub> CeO2sub> flue gas

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The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al2sub>O3sub> with a small amount, wasintroduced into Pb/SiO2sub> catalyst in this study.It has been proved that Al2sub>O3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O3sub> addition was also proposed.

Keywords： Pb/SiO2sub> Al2sub>O3sub> propane dehydrogenation propene stability

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ZnFe2sub>O4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 2, Pages 197-204 doi: 10.1007/s11705-016-1606-y

Abstract: ZnFe O -BiOCl composites were prepared by both hydrothermal and direct precipitation processes and the structures and properties of the samples were characterized by various instrumental techniques. The samples were then used as catalysts for the photocatalytic reduction of CO in cyclohexanol under ultraviolet irradiation to give cyclohexanone (CH) and cyclohexyl formate (CF). The photocatalytic CO reduction activities over the hydrothermally prepared ZnFe O -BiOCl composites were higher than those over the directly-precipitated composites. This is because compared to the direct-precipitation sample, the ZnFe O nanoparticles in the hydrothermal sample were smaller and more uniformly distributed on the surface of BiOCl and so more heterojunctions were formed. Higher CF and CH yields were obtained for the pure BiOCl and BiOCl composite samples with more exposed (001) facets than for the samples with more exposed (010) facets. This is due to the higher density of oxygen atoms in the exposed (001) facets, which creates more oxygen vacancies, and thereby improves the separation efficiency of the electron-hole pairs. More importantly, irradiation of the (001) facets with ultraviolet light produces photo-generated electrons which is helpful for the reduction of CO to ·CO . The mechanism for the photocatalytic reduction of CO in cyclohexanol over ZnFe O -BiOCl composites with exposed (001) facets involves electron transfer and carbon radical formation.

Keywords： reduction of CO2sub> cyclohexanol ZnFe2sub>O4sub> deposited BiOCl facet composite

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Development of H2sub>O/CO2sub> co-electrolysis in solid oxide electrolysis cell

Fan Hui,Song Shidong,Han Minfang

Strategic Study of CAE 2013, Volume 15, Issue 2, Pages 107-112

Abstract: The structure of SOEC, the recent development of high temperature steam/CO2 co-electrolysis from

Keywords： SOEC H2sub>O/CO2sub> co-electrolysis syngas electrolysis efficiency water electrolysis

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Title Author Date Type Operation

All-inorganic TiO/CsAgBiBr composite as highly efficient photocatalyst under visible light irradiation

Journal Article

Cu-doped Bi/Bi2sub>WO6sub> catalysts for efficient N2sub> fixation by photocatalysis

Journal Article

ZnFe2sub>O4sub>/BiVO4sub> Z-scheme heterojunction for efficient visible-light photocatalytic

Journal Article

In-MOF-derived In2sub>S3sub>/Bi2sub>S3sub> heterojunction for enhanced photocatalytic

Journal Article

Interfacial charge transfer and photocatalytic activity in a reverse designed BiO/TiO core-shell

Journal Article

Piezocatalytic performance of FeO−BiMoO catalyst for dye degradation

Journal Article

Enhanced performance of NiF/BiVO photoanode for photoelectrochemical water splitting

Journal Article

Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

Journal Article

A Storage-Driven CO2sub> EOR for a Net-Zero Emission Target

Yueliang Liu, Zhenhua Rui

Journal Article

Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Journal Article

ZnFe2sub>O4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Journal Article

Development of H2sub>O/CO2sub> co-electrolysis in solid oxide electrolysis cell

Fan Hui,Song Shidong,Han Minfang

Journal Article

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